Porphyrin based polyimide ppbpis (ppbpi-pa, ppbpi-pepa and ppbpi-pena); Crosslinked porphyrin based polyimide (ppbpi-pa-cr, ppbpi-pepa-cr, ppbpi-pena-cr) reagent

Porphyrin based polyimide PPBPIs(PPBPI-PA、PPBPI-PEPA and PPBPI-PENA)

Crosslinked porphyrin based polyimide (PPBPI-PA-CR、PPBPI-PEPA-CR、PPBPI-PENA-CR)

In this chapter, the pore parameters and CO2 Adsorption and selectivity . secondly , Ellipsoidal structure of hyperbranched polyimide , It is beneficial to introduce the end capping group to modify it . The spatial configuration of the capped monomer ( Conjugation effect and molecular size ) It plays an important role in optimizing hole parameters , On this basis , We introduce three kinds of alkynyl terminated monoanhydrides with different spatial configurations , Three crosslinked porphyrin based polyimides were prepared (PPBPI-PA-CR、PPBPI-PEPA-CR、PPBPI-PENA-CR). suffer π Stacking effect and molecular size effect , With the increase of conjugation effect and molecular size of capped monoanhydrides , The specific surface area of the uncrosslinked polymer decreases (106.8-8.3 m2 g-1), The specific surface area of the crosslinked polymer increases (1.8-633 m2 g-1). And crosslinked polymers have considerable CO2 Adsorption capacity (1.37、2.01、2.37 mmol g-1)、CO2 Endothermic enthalpy (34.8、27.5、22.6 k J/mol) and CO2/N2(39.83、36.95、40.08) And CO2/CH4(14.13、9.78、10.87) Adsorption selectivity . The appropriate spatial configuration of capped monoanhydrides is an important factor affecting the pore parameters of crosslinked polymers . Again , The different spatial positions of alkynyl groups in the polyimide backbone , It will cause the difference of alkynyl crosslinking sites in the polymer chain .

Porphyrin catalogue ：

5,10,15,20 Four ( Pentafluorophenyl ) porphyrin (TF5PPH2)
Complexes of three ruthenium porphyrins Ru(TPP)(CO),Ru(TPP)(CO)(Py) and Ru(TPP)(CO)(C5H4NCOOH)
Tetra-p-methylphenyl porphyrin (TPP) doping MEH-PPV
Tetra-p-methylphenyl porphyrin (TPP) Doped polyethylene carbazole (PVK)
Photosensitizer tetraphenyl porphyrin zinc (ZnTPP)
β- Nitroporphyrin β-NO2-TPP
β- Nitro copper porphyrin complex (β-NO2-CuTPP)
β- Amino substituted porphyrins β-NH2-TPP
β- Amino substituted porphyrin copper complex (β-NH2-CuTPP)
Amphiphilic block copolymer polyethylene glycol - Diisopropylaminoethyl methacrylate - Tetraphenyl porphyrin (PEG-PDPA-TPP),
Porphyrin semi telechelic polymer photosensitizer (TPP-PEG)
Bauxite fixed load IV ( Yes - Hydroxyphenyl ) Iron porphyrin THPPFe/BM
Bauxite fixed load IV ( Yes - Hydroxyphenyl ) Manganese porphyrin THPPMn/BM
Bauxite fixed load IV ( Yes - Nitrophenyl ) Cobalt porphyrin TNPPCo/BM
Bauxite fixed load IV ( Yes - Nitrophenyl ) Iron porphyrin TNPPFe/BM
Bauxite fixed load IV ( Yes - Nitrophenyl ) Manganese porphyrin TNPPMn/BM
Supramolecular self-assembly materials ([email protected]β-CD)
Four arm star porphyrin chain transfer agent (THPP-DMP4)
Graphene based ternary nanocomposites GO/THPP/PSA
Four (4- Hydroxyphenyl ) Iron porphyrin supported graphene oxide (Fe THPP/GO)
5,10,15,20- Four (4- Hydroxyphenyl ) Porphyrin graphene complex (M-THPP/PSS-rGO,M:Fe3+,Co2+,Ni2+,Mn2+)
5,10,15,20- Four (4- Hydroxyphenyl ) Iron porphyrin graphene complex (Fe3+-THPP/PSS-rGO)

  
This article comes from Xi'an Qiyue biology Xiaobian axc