PXRD, IR, TGA of two-dimensional porphyrin COF (POR COF) /cof (2D pdpor COF) - supplied by Qiyue

Two dimensional porphyrin COF(Por-COF) Introduction to

Covalent organic framework materials (Covalentorganicframeworks,COFs) It is a kind of porous crystalline materials made of light elements connected by covalent bonds , Having a height higher than the surface , Low density , Adjustable aperture and other properties , It has been applied to gas adsorption and separation , catalysis , Optoelectronics and other fields . at present COFs The main research work includes two-dimensional and three-dimensional COFs Topology design ,COFs Functionality and application development of , Among them, three-dimensional COFs It is very challenging to study the construction and functional application of . Porphyrin compounds are a class of organic photoelectric molecules , It has unique photochemical and photophysical properties , It is often used as a building block in the study of structural chemistry and material chemistry . therefore , The research work of this thesis is to introduce metalloporphyrins into three-dimensional space COFs And explore its application in the field of photocatalysis , It mainly includes three parts :1. Two new three-dimensional metalloporphyrins were designed and synthesized COFs(3D-PdPor-COF,3D-NiPor-COF), In addition, for comparison , A novel two-dimensional metalloporphyrin was also synthesized COF(2D-PdPor-COF). The topological structure is determined through structural analysis , Then, a series of characterizations were carried out , Include PXRD, infrared spectrum , Thermogravimetric analysis

 

Porphyrin catalogue ：
   Decanoxy tetraphenyl porphyrin methacrylate (MM-TPP-10C)
Dodecyloxy tetraphenyl porphyrin methacrylate (MM-TPP-12C)
Tetradecyl oxytetraphenyl porphyrin methacrylate (MM-TPP-14C)
Cetyloxy tetraphenyl porphyrin methacrylate (MM-TPP-16C)
Polydodecyl methacrylate porphyrin PM-TPP-12C
Polymethacrylic acid decanoxy porphyrin PM-TPP-10C
Polytetradecyl methacrylate porphyrin PM-TPP-14C
Poly (hexadecane methacrylate) porphyrin PM-TPP-16C
Small molecule monohydroxydodecanoxy porphyrin OH-TPP-12C
5,10,15,20- Four (4- Methoxycarbonylphenyl ) Cobalt porphyrin ( Co-TPPCOOMe)
5,10,15,20- Four (4- Carboxyphenyl ) Cobalt porphyrin (Co-TCPP)
5,10,15,20- Four (3,5- s Methyl phenyl ) porphyrin (MegH2OCPP)
5,10,15,20- Four (3,5- Dicarboxyphenyl ) Metalloporphyrins (M-H8OCPP)
5,10,15,20- Tetrapyridyl phenyl porphyrin (H2TPyP)
5,10,15,20- Four (4- Methoxycarbonylphenyl ) porphyrin (TPPCOOMe)
5,10,15,20- Four (4- Methoxycarbonylphenyl ) Zinc porphyrin (Zn-TPPCOOMe)
 

This article comes from Xi'an Qiyue Xiaobian axc.222.02.17