Crosslinked metalloporphyrin based polyimide ppbpi-h) PPBP Mn; PBP-Fe； PPBPI-Fe-CR； Ppbpi Mn CR product - supplied by Qiyue

Porphyrin based polyimide (PPBPI-H)PPBP-Mn;PBP-Fe Introduction to

There is mechanical stirring in the assembly 、 Nitrogen vent and drying pipe 100mL In three mouth bottle , Join in 5,10,15,20-

Four （4- Aminophenyl ） porphyrin （0.6g,0.8892mmol） and 30mLN- Methyl pyrrolidone . There will be dissolved in nitrogen atmosphere PEPHQDA（0.6033g,0.8892mmol） Of 24mLN- Methyl pyrrolidone solution is put into a constant pressure dropping funnel and dropped into a three mouth bottle , Control the drop acceleration to make the solution in 2～3h Internal dripping is complete . Room temperature reaction overnight , Join in 2.5mL Isoquinoline , Heat up to 120℃ reaction 4h, Continue to heat up to 180℃ reaction 24h, Reduce to room temperature , Discharge in absolute ethanol , Filter and collect the product , And placed in Soxhlet extractor and washed with ethanol 24h. Yield ：80%.

Synthesis of metalloporphyrin based polyimide （PPBPI-Mn、PPBPI-Fe） There is mechanical stirring in the assembly 、 Nitrogen vent and drying pipe 250mL In three mouth bottle , Join in PPBPI-H（0.28g）、 Manganese acetate tetrahydrate （0.725g,2.96mmol） And 80mLN,N- Dimethylacetamide . The reaction was heated to... Under nitrogen 100℃, And react at this temperature 8h. Cool to room temperature , Discharge in deionized water , Filter and collect the product , And use deionized water to wash away the inorganic metal salts that have not been chelated for many times . Yield ：92%.

 

 

  Porphyrin catalogue ：

Linear structure of hydroxyl phenyl porphyrin bonded by side chain PGMA(HPP-PGMA)
The side chain is bonded with manganese porphyrin (MnP) The line shape of PGMA(MnP-PGMA)
POSS Hybrid porphyrin (Porphyrin-POSS)
Black titanium dioxide (bTiO2)/ porphyrin (THPP) Hybrid optoelectronic materials
[email protected] Core shell composite
Phenylporphyrin functionalized glycidyl methacrylate (PP-PGMA)
Hydroxyl phenyl porphyrin functionalized glycidyl methacrylate (HPP-PGMA)
Metalloporphyrins -L- Cysteine self-assembled monolayer electrode NTMPP-L-Cys/Au SAMs(N=Fe,Cu,Co)
carbon loading 5- Monocarboxyl -10,15,20- Triphenyl cobalt porphyrin (CoMCP)
carbon loading 5- Monocarboxyl -10,15,20- Triphenyl iron porphyrin (FeMCP)
carbon loading 5- Monocarboxyl -10,15,20- Triphenylmanganese porphyrin (MnMCP)
carbon loading 5- Monocarboxyl -10,15,20- Triphenyl copper porphyrin (CuMCP)
meso- Four -(4- Trimethylammonium phenyl ) porphyrin (TMAP)
meso- Four (4- Aminophenyl ) porphyrin ( abbreviation T(4-AP)P)
meso Four ( 4 Nitrophenyl ) porphyrin (T( 4-N P)P)
5-(4- Hydroxyphenyl )-10,15.20- Trichlorophenylporphyrin (H2(p-Cl)3POH)
Four ( Yes - Octyl oxy ) Phenylporphyrin [ abbreviation T(p-OO)PPH2
5- (4- Carboxyphenyl ) -10,15,20- Triphenyl porphyrin (CTPP)
5- (4 Aminophenyl ) -10,15,20- Triphenyl porphyrin (ATPP)
5- Acetylthiophenyl -10,15,20- Triphenyl porphyrin ( AcS-TPP)
5,10,15,20- Four -(4- Phenyl sulfonic acid )-21H,23H- porphyrin (H2TPPS)
5,10,15,20- Four (4- Pyridyl )-21H,23H- porphyrin (H2TMPyP)
5-( M-carbonylbenzoic acid )- Aminophenyl -10,15,20- Triphenyl porphyrin (m-CPTPP)
Tetraiodide 5,10,15,20- Four ( Yes -N,N,N Trimethylaniline ) porphyrin (TAPPI)
Four - Yes ( CINNAMOYLOXY ) Phenyl porphyrin cobalt complex (CoTCCOPP)
Four —( Right Gan — Valodipeptide phenyl ) porphyrin (H2L)
  
This article comes from Xi'an Qiyue biology Xiaobian axc